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1. CHEMICAL
PRODUCT & COMPANY IDENTIFICATION
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Manufacturer,
Distributor
Emergency
Telephone Numbers:
BioRenova
CHEMTREC
U.S.
(800)
424-9300
6130 W. Lawrence Ave.
Chicago
,
IL
60630
Emergency Phone: 24 hours
847-791-7779
Phone:
847-791-7779
U.S.
Version
Date: 07/12/2011
MSDS #A650
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2. COMPOSITION
(OSHA HAZARDOUS INGREDIENTS)
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The specific identities
of
certain components of this
formulation are withheld as
trade secrets in accordance
with 29 CFR 1910.1200.
Ingredients Chemical
Formula CAS No.
Percentage
Calcium Peroxide CaO2
1305-79-9 Min. 75.0
Calcium Hydroxide Ca(OH)2
1305-62-0 Max. 25.0
Yeast Extract
NA
8013-01-3 NA
Alcohols, C12-15 Ethoxylated
NA
68131-39-5 NA
Ureaform
NA
9011-05-6 NA
Monopotassium Phosphate KH2PO4
7778-77-0 NA
Methyl Ester
NA
67784-80-9 NA
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3.
HAZARD IDENTIFICATION
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HAZARD SUMMARY
White, free-flowing powder with no odor.
Oxidizer! Contain
all spills. Non-flammable.
See Sections 3,5,6.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
EYES:
Causes severe eye irritation.
SKIN:
May cause skin irritation.
INGESTION: Causes
severe mucous membrane, mouth, throat, esophagus and stomach
irritation.
INHALATION:
Causes respiratory tract and mucous membrane irritation.
ROUTES OF ENTRY:
Eye contact, skin contact, ingestion and inhalation.
TARGET ORGANS:
Eyes, skin, respiratory tract and mucous membranes.
CHRONIC HEALTH EFFECTS
CARCINOGENICITY:
This product does NOT contain compounds known to be carcinogens,
i.e., cause cancer, according to NTP, IARC or OSHA.
MUTAGENCITY: No
information regarding mutagenicity is available.
TERATOGENICITY:
No information regarding teratogenicity is available.
REPRODUCTIVE TOXICITY:
No information regarding reproductive toxicity is available.
MEDICAL CONDITIONS AGGRAVATED BY
EXPOSURE: None known.
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4.
FIRST AID MEASURES
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EYES:
In case of contact, immediately flush eyes with water for at least
15-20 minutes. Lift
upper and lower lids and rinse well under them.
Get immediate medical attention.
SKIN:
Immediately wipe excess material off skin; remove contaminated
clothing and shoes. Then
wash with soap and water. If
heavy contamination has occurred, then discard the clothing in a
manner which limits further exposure.
Otherwise, thoroughly clean contaminated clothing and shoes
before use. Get
medical attention.
INHALATION:
Remove
from exposure. If
individual is not breathing, administer cardiopulmonary
resuscitation (CPR) and get immediate medical attention.
If individual is breathing, but with difficulty, get
medical attention.
INGESTION:
Do not induce vomiting. Do
not give anything by mouth to an unconscious person.
Immediately drink large quantities of milk or water.
Get medical attention.
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5.
FIRE FIGHTING MEASURES
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FLAMMABLE PROPERTIES
Oxidizer!
FLASH POINT: Not
applicable.
METHOD USED: Not
applicable.
FLAMMABLE LIMITS:
Not applicable.
EXTINGUISHING MEDIA: Use
water spray.
FIRE
& EXPLOSION HAZARDS: Thermal decomposition products include oxygen.
When in contact with paper, wood, cloth, and other burnable
materials, may cause spontaneous combustion of the organic
material.
FIRE-FIGHTING
EQUIPMENT: Protect
personnel from skin and respiratory exposure.
Wear self-contained breathing apparatus and personal
protective equipment when fighting fires involving this product.
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6.
ACCIDENTAL RELEASE MEASURES
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LARGE
SPILL: Isolate
hazard area and deny entry to unnecessary or unprotected
personnel. Sweep up
and place in a disposal container.
Rinse spill area with water.
Avoid runoff into storm sewers and ditches which lead to
waterways. Never
discharge directly into a lake, pond, stream, river or other
natural body of water.
SMALL
SPILL: Scoop
up material and place in a disposal container.
Rinse spill area with large amounts of water.
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7.
HANDLING AND STORAGE
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HANDLING:
Wear
appropriate protective clothing.
Avoid prolonged contact with skin and clothing.
Avoid breathing product. After
handling, always wash hands and clothing thoroughly with soap and
water. Avoid contact
with water or humidity.
STORAGE:
Store
in a cool, dry, well ventilated place away from direct sunlight,
heat, cold, metals, sources of ignition, strong reducing agents
and/or acids. Use
approved equipment for transportation of drums to avoid puncturing
or rupturing. Do not
reuse drum or other containers.
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8.
EXPOSURE CONTROL/PERSONAL PROTECTION
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RESPIRATORY
PROTECTION: Use
general room ventilation or local exhaust ventilation to keep
airborne exposure below the TLV.
If ventilation is not adequate to keep the airborne
concentration below the TLV, wear a dust mask.
SKIN PROTECTION: Wear
impervious gloves, boots and apron.
EYE
PROTECTION: Use
chemical safety goggles or a full face shield, as well as an eye
wash shower, and washing facilities near the work area.
EXPOSURE
GUIDELINES: Exposure
guidelines have not been established for the product as a whole.
The following are exposure guidelines for component(s) of
this product:
COMPONENT
OSHA PEL-TWA
ACGIH TLV-TWA
Particulates,
not
15 mg/m3 (total dust)
10 mg/m3 (inhalable particulate)
otherwise
classified
ENGINEERING
CONTROLS: Use
only with adequate ventilation.
Local exhaust ventilation may be necessary for some
operations.
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9.
PHYSICAL AND CHEMICAL PROPERTIES
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APPEARANCE: White, free-flowing powder
ODOR:
None
BOILING POINT: Not
established
SOLUBILITY IN WATER:
140 g/L at 751F to slightly soluble
SPECIFIC GRAVITY:
1.0 -2.9 g/cc (bulk density)
MELTING POINT:
Decomposes at 1221F
% VOLATILE:
None
pH (1% solution): 10.4 - 10.6, 12.0 - 13.0 in slurry form
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10. STABILITY
AND REACTIVITY
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STABILITY:
(CONDITIONS
TO AVOID) Stable. Avoid
excessive heat, sources of ignition, direct sunlight and
moisture.
INCOMPATIBILITY:
(SPECIFIC MATERIALS TO AVOID) Avoid contact with acids, bases,
reducing agents, organic materials, flammable substances and
metals (metallic ions).
HAZARDOUS
DECOMPOSITION PRODUCTS: Decomposition products include oxygen and heat.
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11. TOXICOLOGICAL
INFORMATION
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Toxicological
information is listed below.
LD50 (oral) rat: 1034 mg/kg
LD50 (dermal) rabbit: >2000 mg/kg
LC0 (1 hr.) rat: >4580 mg/m3
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12. ECOLOGICAL
INFORMATION
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ENVIRONMENTAL
FATE: Degradation
products in water include sodium carbonate, carbon dioxide,
bicarbonate, carbonate and hydrogen peroxide.
Hydrolysis will occur in soil.
AQUATIC
TOXICITY: Aquatic
toxicity data is listed below.
LC50 Pimephales promelas: 70.7 mg/L
NOEC (96 hrs.) Pimephales promelas: 1 mg/L
EC50 Daphnia pulex: 4.9 mg/L
NOEC (48 hrs.) Daphnia pulex: 1 mg/L
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13. DISPOSAL
CONSIDERATIONS
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RCRA HAZARD CLASS: D001
WASTE
MANAGEMENT INFORMATION: Any disposal practice must be in compliance with local,
state and federal laws and regulations (contact local or state
environmental agency for specific rules).
Do not dump into sewers, on the ground or into any body
of water.
NOTE:
Chemical
additions, processing, use or otherwise altering this product
may render the disposal considerations invalid, inaccurate and
otherwise inappropriate.
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14. TRANSPORT
INFORMATION
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TRANSPORTATION
AND HAZARDOUS MATERIALS DESCRIPTION
For domestic shipments:
DOT SHIPPING NAME: Oxidizing solid, n.o.s. (Contains sodium carbonate peroxyhydrate)
UN ID NO.:
1479
HAZARD CLASS, LABEL AND PACKAGING GROUP: 5.1 (Oxidizer); II
EMERGENCY RESPONSE GUIDEBOOK NO.: 140
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15. REGULATORY
INFORMATION
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OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200): According
to the OSHA Hazard Communication Standard this product is
considered hazardous because it contains Component A.
CERCLA/SUPERFUND
(40 CFR 117, 302): This product contains the following regulated compounds:
None.
SARA
TITLE III, Section 302 Extremely Hazardous Substances (40 CFR
355, Appendix A):
None.
SARA
TITLE III, Section 311/312
Hazard Category (40 CFR 370.2):
Immediate (acute) health hazard; fire hazard.
Substance: Calcium peroxide, calcium hydroxide and sodium
carbonate peroxhydrate
SARA
TITLE III, Section 313 INFORMATION (40 CFR 372): This
product contains the following regulated compounds subject to
the reporting requirements of Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986.
COMPONENT
CAS NO.
WT. %
None
Not applicable
Not applicable
TOXIC
SUBSTANCES CONTROL ACT (TSCA): The ingredients of this product are all on the TSCA Inventory
list.
CALIFORNIA
PROPOSITION 65: The
following statement is made in order to comply with the California
Safe Drinking Water and Toxic Enforcement Act of 1986: Chemicals
known to the State of
California
to
cause cancer are NOT present in this product at levels which pose
a Significant Risk@,
[22
CCR 12705 (b)].
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16. OTHER
INFORMATION
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NFPA Rating
HMIS Rating
Fire
0
Health
2
Health
2
Flammability
0
Reactivity
1
Reactivity
1
Hazard
OX
Protection
E1
1
The HMIS Rating is intended to be established by the employer, as
the employer is most aware of the employees use or application of
the product, work environment and available personal protective
equipment. This rating
is intended for guidance only.
Information
given herein is offered in good faith as accurate, but without
guarantee. Conditions
of use and suitability of the product for particular uses are
beyond our control; all risks of use of the product are therefore
assumed by the user and we expressly disclaim all warranties of
every kind and nature, including warranties of merchantability and
fitness for a particular purpose in respect to the use or
suitability of the product.
Nothing is intended as a recommendation for uses which
infringe valid patents or as extending license under valid
patents. Appropriate
warnings and safe handling procedures should be provided to
handlers and users.
REASON
FOR ISSUE: New product.
SUPERSEDES: Not applicable.
PREPARED BY: Product Stewardship Coordinator
TECHNICAL DEPARTMENT
